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Synonyms: None
CAS No.: Not applicable to mixtures.
Molecular Weight: Not applicable to mixtures.
Chemical Formula: Not applicable to mixtures.
Product Codes: 5757, 5792
Ingredient CAS No Percent Hazardous --------------------------------------- ------------ ------- --------- Zirconium, Dichlorooxo- 7699-43-6 < 2% Yes Hydrogen Chloride 7647-01-0 < 2% Yes Water 7732-18-5 > 96% No
Emergency Overview
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DANGER! CORROSIVE. LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE. MAY BE FATAL IF SWALLOWED OR INHALED. VAPOR IRRITATING TO EYES AND RESPIRATORY TRACT. INHALATION MAY CAUSE LUNG DAMAGE.
J.T. Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience)
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Health Rating: 3 - Severe (Life)
Flammability Rating: 0 - None
Reactivity Rating: 1 - Slight
Contact Rating: 3 - Severe (Corrosive)
Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
Storage Color Code: White (Corrosive)
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Potential Health Effects
----------------------------------
The following hazards are for concentrated solutions. Hazards of less concentrated solutions may be reduced. Degree of hazard for reduced concentrations is not currently addressed in the available literature.
Inhalation:
Corrosive! Inhalation of vapors can cause coughing, choking, inflammation of the nose, throat, and upper respiratory tract, and in severe cases, pulmonary edema, circulatory failure, and death.
Ingestion:
Corrosive! Swallowing can cause immediate pain and burns of the mouth, throat, esophagus and gastrointestinal tract. May cause nausea, vomiting, and diarrhea, and in severe cases, death.
Skin Contact:
Corrosive! Can cause redness, pain, and severe skin burns. Concentrated solutions cause deep ulcers and discolor skin. May produce skin sensitization or allergic skin reactions.
Eye Contact:
Corrosive! Vapors are irritating and may cause damage to the eyes. Contact may cause severe burns and permanent eye damage.
Chronic Exposure:
Long-term exposure to concentrated vapors may cause erosion of teeth. Long term exposures seldom occur due to the corrosive properties of the acid. Chronic exposure may cause skin and respiratory effects.
Aggravation of Pre-existing Conditions:
Persons with pre-existing skin disorders or eye disease may be more susceptible to the effects of this substance.
First aid procedures given apply to concentrated solutions. Exposures to dilute solutions may not require these extensive first aid procedures.
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Fire:
Not considered to be a fire hazard. Extreme heat or contact with metals can release flammable hydrogen gas.
Explosion:
Contact of concentrated solutions with most metals causes formation of flammable and explosive hydrogen gas.
Fire Extinguishing Media:
Water or water spray. Neutralize with soda ash or slaked lime.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. Structural firefighter's protective clothing is ineffective for fires involving hydrochloric acid. Stay away from ends of tanks. Cool tanks with water spray until well after fire is out.
Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Neutralize with alkaline material (soda ash, lime), then absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer! US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802.
J. T. Baker NEUTRASORB(tm) or TEAM(tm) 'Low Na+' acid neutralizers are recommended for spills of this product.
Store in a cool, dry, ventilated storage area with acid resistant floors and good drainage. Protect from physical damage. Keep out of direct sunlight and away from heat, water, and incompatible materials. Do not wash out container and use it for other purposes. When diluting, the acid should always be added slowly to water and in small amounts. Never use hot water and never add water to the acid. Water added to acid can cause uncontrolled boiling and splashing. When opening metal containers, use non-sparking tools because of the possibility of hydrogen gas being present. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product.
Airborne Exposure Limits:
For Hydrochloric acid:
- OSHA Permissible Exposure Limit (PEL):
5 ppm (Ceiling)
- ACGIH Threshold Limit Value (TLV):
5 ppm (STEL/Ceiling)
For Zirconium Oxychloride Component:
-OSHA Permissible Exposure Limit (PEL):
Zirconium compounds as Zr: 5 mg/m3 (TWA)
-ACGIH Threshold Limit Value (TLV):
Zirconium & compounds as Zr: 5 mg/m3 (TWA), 10 mg/m3 (STEL)
A4, Not classifiable as a human carcinogen
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
Hydrochloric Acid Component: If the exposure limit is exceeded, a full facepiece respirator with an acid gas cartridge may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres. For Zirconium Oxychloride Component: If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Rubber or neoprene gloves and additional protection including impervious boots, apron, or coveralls, as needed in areas of unusual exposure to prevent skin contact.
Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Appearance:
Clear, colorless liquid.
Odor:
Hydrochloric acid odor.
Solubility:
Complete (100%)
Specific Gravity:
No information found.
pH:
No information found.
% Volatiles by volume @ 21C (70F):
ca. 98
Boiling Point:
No information found.
Melting Point:
No information found.
Vapor Density (Air=1):
No information found.
Vapor Pressure (mm Hg):
No information found.
Evaporation Rate (BuAc=1):
No information found.
Stability:
Stable under ordinary conditions of use and storage. Containers may burst when heated.
Hazardous Decomposition Products:
When heated to decomposition, emits toxic hydrogen chloride fumes and will react with water or steam to produce heat and toxic and corrosive fumes. Thermal oxidative decomposition produces toxic chlorine fumes and explosive hydrogen gas. Toxic fumes of the contained metal may be released when heated to decomposition.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
A strong mineral acid, concentrated hydrochloric acid is incompatible with many substances and highly reactive with strong bases, metals, metal oxides, hydroxides, amines, carbonates and other alkaline materials. Incompatible with materials such as cyanides, sulfides, sulfites, and formaldehyde.
Conditions to Avoid:
Heat, direct sunlight, incompatibles.
Hydrochloric acid: Inhalation rat LC50: 3124 ppm/1H; Oral rabbit LD50: 900 mg/kg. Investigated as a tumorigen, mutagen, reproductive effector.
For Zirconium Oxychloride Component:
Oral rat LD50: 2950 mg/kg. Investigated as a tumorigen.
--------\Cancer Lists\------------------------------------------------------
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
------------------------------------ ----- ----------- -------------
Zirconium, Dichlorooxo- (7699-43-6) No No None
Hydrogen Chloride (7647-01-0) No No 3
Water (7732-18-5) No No None
Environmental Fate:
For Hydrochloric Acid (Concentrated Solutions):
When released into the soil, this material is not expected to biodegrade. When released into the soil, this material may leach into groundwater.
Environmental Toxicity:
For Hydrochloric Acid (Concentrated Solutions):
This material may be toxic to aquatic life. LC50 Shrimp: 100-300 ppm/48-hr/salt water; LC100 trout: 10 mg/l/24-hr; TLm mosquito fish: 282 ppm/96-hr.
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
Domestic (Land, D.O.T.)
-----------------------
Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (HYDROGEN CHLORIDE)
Hazard Class: 8
UN/NA: UN3264
Packing Group: III
Information reported for product/size: 100ML
International (Water, I.M.O.)
-----------------------------
Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (HYDROGEN CHLORIDE)
Hazard Class: 8
UN/NA: UN3264
Packing Group: III
Information reported for product/size: 100ML
International (Air, I.C.A.O.)
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Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (HYDROGEN CHLORIDE)
Hazard Class: 8
UN/NA: UN3264
Packing Group: III
Information reported for product/size: 100ML
--------\Chemical Inventory Status - Part 1\---------------------------------
Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ---------
Zirconium, Dichlorooxo- (7699-43-6) Yes Yes Yes Yes
Hydrogen Chloride (7647-01-0) Yes Yes Yes Yes
Water (7732-18-5) Yes Yes Yes Yes
--------\Chemical Inventory Status - Part 2\---------------------------------
--Canada--
Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ---- -----
Zirconium, Dichlorooxo- (7699-43-6) Yes Yes No Yes
Hydrogen Chloride (7647-01-0) Yes Yes No Yes
Water (7732-18-5) Yes Yes No Yes
--------\Federal, State & International Regulations - Part 1\----------------
-SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- --------------
Zirconium, Dichlorooxo- (7699-43-6) No No No No
Hydrogen Chloride (7647-01-0) 5000 500* Yes No
Water (7732-18-5) No No No No
--------\Federal, State & International Regulations - Part 2\----------------
-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ------
Zirconium, Dichlorooxo- (7699-43-6) No No No
Hydrogen Chloride (7647-01-0) 5000 No No
Water (7732-18-5) No No No
Chemical Weapons Convention: No TSCA 12(b): No CDTA: No
SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: No
Reactivity: No (Mixture / Liquid)
Australian Hazchem Code: No information found.
Poison Schedule: No information found.
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.
NFPA Ratings: Health: 3 Flammability: 0 Reactivity: 1
Label Hazard Warning:
DANGER! CORROSIVE. LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE. MAY BE FATAL IF SWALLOWED OR INHALED. VAPOR IRRITATING TO EYES AND RESPIRATORY TRACT. INHALATION MAY CAUSE LUNG DAMAGE.
Label Precautions:
Do not get in eyes, on skin, or on clothing.
Do not breathe vapor or mist.
Use only with adequate ventilation.
Keep container closed.
Wash thoroughly after handling.
Label First Aid:
In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. In all cases get medical attention immediately.
Product Use:
Laboratory Reagent.
Revision Information:
MSDS Section(s) changed since last revision of document include: 3, 16.
Disclaimer:
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AIIR provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. AIIR MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, AIIR WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.
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